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ACID,BASE,SALTLoading...
Acid-Base Properties of Salts
Salts, when placed in water, will often react with the water to produce H3O+ or OH-. This is known as a hydrolysis reaction. Based on how strong the ion acts as an acid or base, it will produce varying pH levels. When water and salts react, there are many possibilities due to the varying structures of salts. A salt can be made of either a weak acid and strong base, strong acid and weak base, a strong acid and strong base, or a weak acid and weak base. The reactants are composed of the salt and the water and the products side is composed of the conjugate base (from the acid of the reaction side) or the conjugate acid (from the base of the reaction side). In this section of chemistry, we discuss the pH values of salts based on several conditions.
When is a salt solution basic or acidic?
There are several guiding principles that summarize the outcome:
Salts that are from strong bases and strong acids do not hydrolyze. The pH will remain neutral at 7. Halides and alkaline metals dissociate and do not affect the H+ as the cation does not alter the H+ and the anion does not attract the H+ from water. This is why NaCl is a neutral salt. In General: Salts containing halides (except F-) and an alkaline metal (except Be2+) will dissociate into spectator ions.
Salts that are from strong bases and strong acids do not hydrolyze. The pH will remain neutral at 7. Halides and alkaline metals dissociate and do not affect the H+ as the cation does not alter the H+ and the anion does not attract the H+ from water. This is why NaCl is a neutral salt. In General: Salts containing halides (except F-) and an alkaline metal (except Be2+) will dissociate into spectator ions.
Acid-Base Properties of Salts
Salts, when placed in water, will often react with the water to produce H3O+ or OH-. This is known as a hydrolysis reaction. Based on how strong the ion acts as an acid or base, it will produce varying pH levels. When water and salts react, there are many possibilities due to the varying structures of salts. A salt can be made of either a weak acid and strong base, strong acid and weak base, a strong acid and strong base, or a weak acid and weak base. The reactants are composed of the salt and the water and the products side is composed of the conjugate base (from the acid of the reaction side) or the conjugate acid (from the base of the reaction side). In this section of chemistry, we discuss the pH values of salts based on several conditions.
When is a salt solution basic or acidic?
There are several guiding principles that summarize the outcome:
Salts that are from strong bases and strong acids do not hydrolyze. The pH will remain neutral at 7. Halides and alkaline metals dissociate and do not affect the H+ as the cation does not alter the H+ and the anion does not attract the H+ from water. This is why NaCl is a neutral salt. In General: Salts containing halides (except F-) and an alkaline metal (except Be2+) will dissociate into spectator ions.
Salts that are from strong bases and strong acids do not hydrolyze. The pH will remain neutral at 7. Halides and alkaline metals dissociate and do not affect the H+ as the cation does not alter the H+ and the anion does not attract the H+ from water. This is why NaCl is a neutral salt. In General: Salts containing halides (except F-) and an alkaline metal (except Be2+) will dissociate into spectator ions.
Salts that are from strong bases and weak acids do hydrolyze, which gives it a pH greater than 7. The anion in the salt is derived from a weak acid, most likely organic, and will acceptthe proton from the water in the reaction. This will have the water act as an acid that will, in this case, leaving a hydroxide ion (OH-). The cation will be from a strong base, meaning from either the alkaline or alkaline earth metals and, like before, it will dissociate into an ion and not affect the H+.
Salts of weak bases and strong acids do hydrolyze, which gives it a pH less than 7. This is due to the fact that the anion will become a spectator ion and fail to attract the H+, while the cation from the weak base will donate a proton to the water forming a hydronium ion.
Salts from a weak base and weak acid also hydrolyze as the others, but a bit more complex and will require the Ka and Kb to be taken into account.Whichever is the stronger acid or weak will be the dominate factor in determining whether it is acidic or basic. The cation will be the acid, and the anion will be the base and will form either form a hydronium ion or a hydroxide ion depending on which ion reacts more readily with the water.
Salts of weak bases and strong acids do hydrolyze, which gives it a pH less than 7. This is due to the fact that the anion will become a spectator ion and fail to attract the H+, while the cation from the weak base will donate a proton to the water forming a hydronium ion.
Salts from a weak base and weak acid also hydrolyze as the others, but a bit more complex and will require the Ka and Kb to be taken into account.Whichever is the stronger acid or weak will be the dominate factor in determining whether it is acidic or basic. The cation will be the acid, and the anion will be the base and will form either form a hydronium ion or a hydroxide ion depending on which ion reacts more readily with the water.
Salts of Polyprotic Acids
Do not be intimidated by the salts of polyprotic acids. Yes, they're bigger and "badder" then most other salts. But they can be handled the exact same way as other salts, just with a bit more math. First of all, we know a few things:
Do not be intimidated by the salts of polyprotic acids. Yes, they're bigger and "badder" then most other salts. But they can be handled the exact same way as other salts, just with a bit more math. First of all, we know a few things:
Salts that are from strong bases and weak acids do hydrolyze, which gives it a pH greater than 7. The anion in the salt is derived from a weak acid, most likely organic, and will acceptthe proton from the water in the reaction. This will have the water act as an acid that will, in this case, leaving a hydroxide ion (OH-). The cation will be from a strong base, meaning from either the alkaline or alkaline earth metals and, like before, it will dissociate into an ion and not affect the H+.
Salts of weak bases and strong acids do hydrolyze, which gives it a pH less than 7. This is due to the fact that the anion will become a spectator ion and fail to attract the H+, while the cation from the weak base will donate a proton to the water forming a hydronium ion.
Salts from a weak base and weak acid also hydrolyze as the others, but a bit more complex and will require the Ka and Kb to be taken into account.Whichever is the stronger acid or weak will be the dominate factor in determining whether it is acidic or basic. The cation will be the acid, and the anion will be the base and will form either form a hydronium ion or a hydroxide ion depending on which ion reacts more readily with the water.
Salts of weak bases and strong acids do hydrolyze, which gives it a pH less than 7. This is due to the fact that the anion will become a spectator ion and fail to attract the H+, while the cation from the weak base will donate a proton to the water forming a hydronium ion.
Salts from a weak base and weak acid also hydrolyze as the others, but a bit more complex and will require the Ka and Kb to be taken into account.Whichever is the stronger acid or weak will be the dominate factor in determining whether it is acidic or basic. The cation will be the acid, and the anion will be the base and will form either form a hydronium ion or a hydroxide ion depending on which ion reacts more readily with the water.
Salts of Polyprotic Acids
Do not be intimidated by the salts of polyprotic acids. Yes, they're bigger and "badder" then most other salts. But they can be handled the exact same way as other salts, just with a bit more math. First of all, we know a few things:
Do not be intimidated by the salts of polyprotic acids. Yes, they're bigger and "badder" then most other salts. But they can be handled the exact same way as other salts, just with a bit more math. First of all, we know a few things:
It's still just a salt. All of the rules from above still apply. Luckily, since we're dealing with acids, the pH of a salt of polyprotic acid will always be greater than 7.
The same way that polyprotic acids lose H+ stepwise, salts of polyprotic acids gain H+ in the same manner, but in reverse order of the polyprotic acid.
Take for example dissociation of H2CO3, carbonic acid.
The same way that polyprotic acids lose H+ stepwise, salts of polyprotic acids gain H+ in the same manner, but in reverse order of the polyprotic acid.
Take for example dissociation of H2CO3, carbonic acid.
This means that when calculating the values for Kb of CO32-, the Kb of the first hydrolysis reaction will be K
